The difference between psi and bar goes beyond your favorite metric system. The truth is that choosing one system or another could make a scuba diver’s life easier. At least, sometimes.
For example, using the metric system, it is easier to calculate the liters of air left in the bottle. Scuba tanks are usually filled at 200 bar pressure, and bottles have an air capacity of 10 l., 12 l., 15 l., or 18 l. If you multiply the bars left in your tank by the liters it has, you will know how many liters of air you have left. However, more complicated calculations are needed to know the cubic feet left using the imperial system. Just remember 1 liter is equivalent to 0.0353147 ft3, and you will understand why.
On the other hand, in technical cave diving, users often prefer to use tanks that express the measurement in psi. This is due to the three-thirds rule (one-third of the gas is used for the outbound trip, one-third is for the return trip, and the last one-third is a safety reserve). Since the tanks are usually filled up to 3000 psi, it is much easier to make the calculations and knows when to come back. Don’t you think so?